The supermodel stormed out of the GQ Awards in true diva style after host James Nesbitt cheekily implied to the audience he'd had intimate relations with her.
Minutes later she was seem flouncing out of the backstage interview room and barging past Lily Allen, uttering: 'He’s so****ing rude,' before adding that she would ‘never come to one of these ****ing award ceremonies again'.
Scroll down to see an exclusive video of Kate...
Heading for the exit: Kate stormed past her embarrassed-looking friend Lily Allen as she stormed out of the GQ Awards last night
Alone: Lily was left cringing after Kate's dramatic exit who was angered by a joke by host James Nesbitt who implied he'd had intimate relations with her
Unfortunately for the 35-year-old her exit was caught on camera by a television crew who were filming rap star Dizzee Rascal and Lily at the time. Lily, who Kate had earlier presented the Woman of the Year trophy to, could only manage a nervous giggle as her friend headed for the exit.
An irate Moss was then seen re-emerging and demanding someone find her lip-stick which she had mislaid in her temper.
Gritted teeth: Kate looked like she'd rather be elsewhere as she stood behind her friend Lily clutching her Woman of the Year gong at the GQ Awards last night
Controversial: James Nesbitt offended Kate with his quip to the crowd
Blemishes: Kate's skin was showing the strain of her partying lifestyle
The dramatic scenes were sparked after Kate and Lily left the stage and Nesbitt then told the audience: 'Kate Moss has still got it. Well, she should do, I gave it to her just before she came on stage.'
After some muted laughter from the awards show guests, he added: 'What? I'm talking about my telephone number.'
As she left London's Royal Opera House, she was pictured being bundled into a taxi, propped up by rocker boyfriend Jamie Hince.
After staring the day with lunch at Claridge's in Mayfair, she was unable to hide her spotty skin as she made her getaway last night, which was showing the strain of what had been a long day for the notorious hard-partying model.
It paved the way for what turned out to be an embarrassing night, which saw her launch herself into an impromptu pole-dance at the back of the Royal Opera House after arriving late for the event.
Enlarge 
As she wrapped her slender figure around a column at the venue, she danced to the music and slipped off her black satin jacket, which caught on her wrist and dragged on the floor.
Time for bed? Kate arrives back at Claridge's hotel after the event
While doing her routine her dress rode up and she narrowly avoided flashing her underwear.
When she joined Lily in the winner's room to celebrate the singer picking up the Woman of the Year trophy, she looked like she would rather be elsewhere.
Clearly having sat though 20 winners collecting their awards and making their acceptance speeches had proved rather tiresome for the mother-of-one.
Earlier she admitted 'being terrible at these things' before presenting Lily with her award on stage.
As Lily smiled for photographers clutching her trophy, Kate leaned on the backdrop and let her head roll back.
Lily's composed display came in stark contrast to last year's GQ Awards when the star had a drunken on-stage row with Elton John as the pair hosted the ceremony.
She told him to 'f*** off' after he commented that she had been drinking a lot, before he quipped back that he could 'snort' her 'under the table'.
Last night was a different affair, however, and Lily, dressed in a black sheer dress, left the bad behaviour to Kate.
Rushing in: Kate and boyfriend Jamie Hince hurry into the Royal Opera House
She also interrupted Dizzee Rascal being interviewed in a stairwell of the venue as she ran around trying to find her lipstick before making her hasty exit back to Claridge's.
Lily and Kate struck up a friendship earlier this year and have been spending increasing amounts of time together.
Private dancer: Kate cavorts around a column in the Royal Opera House as she watches the GQ Men of the Year Awards
Strike a pose: The Croydon model tries to take off her jacket
Kate, who has made no secret of her wish for a rock career, has been supportive of Lily's new album and attended several of her gigs in the capital.
In March, the pair both attended the Chanel fashion show together - the French fashion house which both have modelled for.
Mingling: Kate talks to Hollywood lothario Mickey Rourke
While Kate is preparing to release her ninth collection for TopShop, Lily designed just one for rival high street store New Look, which failed to match Kate's impressive sales.
However, Lily later insisted she had nothing but praise for the model after she rescued her from bullies at the Glastonbury Festival several years ago.
Rushing out: Jamie bundles Kate into a waiting car after her sulky exit
Cover-up: Is Jamie trying to hide Kate's blemishes or her blushes?
'They stabbed me in the ear with a beer can and cut my ear open, I also had two black eyes - it was a bit of a nightmare.'
Kate wasn't the only model at last night's ceremony: also in attendance were Daisy Lowe and Rosie Huntingdon-Whiteley.
Starting early: Kate Moss seen yesterday afternoon going for lunch at Claridge's